(E)-N′-(4-Bromobenzylidene)-2-(8-quinolyloxy)acetohydrazide monohydrate

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The crystal of the title Schiff base compound, C(20)H(18)ClN(3)O(3)·H(2)O, was twinned by a twofold rotation about (100). The asymmetric unit contains two crystallographically independent mol-ecules with similar conformations, and two water mol-ecules. The C=N-N angles of 115.7 (6) and 116.2 (6)° are significantly smaller than the ideal value of 120° expected for sp(2)-hybridized N atoms and th...

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N′-[(E)-4-Bromo­benzyl­idene]-1-benzofuran-2-carbohydrazide monohydrate

The title compound, C(16)H(11)BrN(2)O(2)·H(2)O, exists in a trans conformation with respect to the N=C bond [1.2815 (14) Å] and the benzofuran ring system forms a dihedral angle of 2.96 (5)° with the benzene ring. In the crystal, the ketone O atom accepts two O-H⋯O and one C-H⋯O hydrogen bond, and the water O atom accepts an N-H⋯O inter-action. Together, these lead to infinite layers lying para...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809020418